EXPERIMENTAL SECTIONGeneral Experim

EXPERIMENTAL SECTION
General Experimental Procedures. Optical rotations were
measured on a Perkin-Elmer model 241 polarimeter. IR spectra
were run on a JASCO FT/IR-410 spectrometer, equipped with a
Specac Silver Gate ATR system by applying a film on a germanium
plate. 1D- and 2D-NMR spectra were recorded on a Bruker DRX-500
MHz NMR spectrometer. Chemical shifts (δ) are expressed in ppm
with reference to the solvent signals (CDCl3; 1H: 7.24 ppm; 13C:
77.00 ppm), and coupling constants (J) are reported in Hz. All NMR
experiments were obtained by using standard pulse sequences supplied
by the vendor. HRTOFMS and MS/MS spectra were recorded on a
Micromass QTOF-2 spectrometer. EIMS and HREIMS spectra were
recorded on a Finnigan MAT 95 spectrometer. Column chromatography
was carried out on silica gel (200−400 mesh, Natland
International Corporation). Reversed-phase flash chromatography
was accomplished with RP-18 silica gel (40−63 μm, EM Science),
and reversed-phase HPLC was carried out on a Waters 600E Delivery
System pump, equipped with a Waters 996 photodiode detector and a
GROM-Saphir 110 C18 column (120 Å, 12 μm, 300 × 40 mm), or a
Phenomenex, LUNA-C18 column (12 μm, 250 × 50 mm). Thin-layer
chromatography was performed on Whatman glass-backed plates
coated with 0.25 mm layers of silica gel 60.

ผลลัพธ์ (อังกฤษ) 2:

EXPERIMENTAL SECTION
General Experimental Procedures. Optical Rotations were
measured on Perkin-Elmer Model 241 Polarimeter A. IR Spectra
were FT/IR-410 Run on A JASCO Spectrometer, equipped with A.
Specac Silver Gate ATR System by applying A Film on A Germanium.
Plate. 1D-and 2D-NMR Spectra were A Bruker DRX-500 Recorded on.
MHz NMR Spectrometer. Chemical shifts (N) are expressed in PPM.
Solvent with Reference to The Signals (CDCl3; 1H: 24.07 PPM; 13C:.
77.00 PPM), and coupling constants (J) are Reported in Hz. All NMR
experiments were obtained by using standard Supplied Pulse sequences.
by The Vendor. HRTOFMS and MS / MS Spectra were Recorded on A.
Micromass QTOF-2 Spectrometer. EIMS and HREIMS were Spectra
Recorded on A Finnigan MAT 95 Spectrometer. Column chromatography
was carried out on Silica Gel (200-400 Mesh, Natland.
International Corporation). Reversed-Phase Flash chromatography
was accomplished with RP-18 Silica Gel (40-63 m, EM Science),.
and Reversed-Phase HPLC was carried out on A Waters 600E Delivery.
System Pump, equipped with A Waters 996 Photodiode Detector and A.
GROM- Saphir 110 C18 Column (120 Å, 12 m, 300 × 40 mm), or A.
Phenomenex, LUNA-C18 Column (12 m, 250 × 50 mm). Thin-Layer
chromatography was performed on Whatman Glass-backed Plates.
coated with layers of Silica Gel 60 12:25 mm.

ผลลัพธ์ (อังกฤษ) 3:

EXPERIMENTAL SECTION
General Experimental Procedures. Optical rotations were
measured on a Perkin-Elmer model 241, polarimeter. IR spectra
were run on a JASCO FT / IR-410 spectrometer equipped with, a
Specac Silver Gate ATR system by applying a film. On a germanium
plate. 1D - and 2D-NMR spectra were recorded on a Bruker DRX-500
MHz NMR spectrometer. Chemical shifts (δ). Are expressed in PPM
.With reference to the solvent signals (CDCl3; 1H: 7.24 ppm; 13C:
77.00 ppm), and coupling constants (J) are reported in. Hz. All NMR
experiments were obtained by using standard pulse sequences supplied
by the vendor. HRTOFMS and MS / MS spectra. Were recorded on a
Micromass QTOF-2 spectrometer. EIMS and HREIMS spectra were
recorded on a Finnigan MAT 95, spectrometer. Column chromatography
.Was carried out on silica gel (200 −, 400 mesh Natland
International Corporation). Reversed-phase flash chromatography
was. Accomplished with RP-18 silica gel (40 − 63, thermal m EM Science),
and reversed-phase HPLC was carried out on a Waters 600E Delivery
System. Pump equipped with, a Waters 996 photodiode detector and a
GROM-Saphir 110 C18 column (120 BC, 12 thermal m, 300 × 40 mm), or, a
PhenomenexLUNA-C18 column (12, thermal m 250 × 50 mm). Thin-layer
chromatography was performed on Whatman Glass-backed plates
coated with 0.25 mm. Layers of silica gel 60.