Carbohydrate as a kind of important chiral scaffold is widely recognized for its obvious advantages cheap and
readily, available A new type of prolinamide organocatalysts derived from, carbohydrate was synthesized, in
high yield and the, novel organocatalysts Were applied to the direct asymmetric aldol reactions of cyclohexanone
and various aromatic aldehydesThe corresponding aldol products were obtained in high yields (up to 99%) with
excellent diastereoselectivities (up to N 98: 2 DR) and enantioselectivities (up to 97% EE) under mild reaction
conditions
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