The effect of chloride ions upon the pH within the pit was not taken into account. These
and other factors will significantly affect the balance between the production and loss of
hydrogen ions, and therefore the internal pH, of a real pit. The
deterministic nature of the product of internal pit pit depth and current density suggested by Galvele
] [26 therefore cannot be applied to real pits.
This is demonstrated by two current traces of stable pits, pits that cause that is a gradual increase in the measured potentiostatically
current, that are displayed in Figs, 1 and 2.
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