คำศัพท์เฉพาะทางเคมีThe formal synth

คำศัพท์เฉพาะทางเคมีThe formal synthesis of pinnaic acid (1) is summarized
in Scheme 2. Selective silylation of the diol 12 with
TBDPSCl, Et3N, and catalytic DMAP afforded 13 in 87%
yield. Jones oxidation of 13 furnished carboxylic acid 14,
which was subjected to a Curtius rearrangement with
diphenyl phosphoryl azide (DPPA)17 and t-BuOH to afford
10 in 51% yield for the two steps

ผลลัพธ์ (อังกฤษ) 1:

The terminology of The formal chemical synthesis pinnaic acid (1) is summarized.in Scheme 2. Selective silylation of the diol 12 withTBDPSCl, Et3N, and catalytic DMAP afforded 13 in 87%yield. Jones oxidation of 13 furnished carboxylic acid 14,which was subjected to a Curtius rearrangement withdiphenyl phosphoryl azide (DPPA)17 and t-BuOH to afford10 in 51% yield for the two steps

ผลลัพธ์ (อังกฤษ) 2:

The formal terminology, chemical synthesis of Pinnaic acid (1) is Summarized
in Scheme 2. Selective Silylation of the diol 12 with
TBDPSCl, Et3N, and catalytic DMAP afforded 13 in 87%
yield. Jones oxidation of 13 furnished carboxylic acid 14,.
which was subjected to a Curtius Rearrangement with
diphenyl phosphoryl azide (DPPA) 17 and T-BuOH to afford
10 in 51% yield for the Two steps.

ผลลัพธ์ (อังกฤษ) 3:

Chemical terminology The formal synthesis of pinnaic acid (1) is summarized
in Scheme 2. Selective silylation of the diol 12 with
TBDPSCl,, Et3N and catalytic, DMAP afforded 13 in 87%
yield. Jones oxidation of 13 furnished carboxylic, acid 14
which was subjected. To a Curtius rearrangement with
diphenyl phosphoryl azide (DPPA) 17 and t-BuOH to afford
.10 in 51% yield for the two steps.